Why are simple asphyxiants especially dangerous in confined spaces?
WHMIS: Physical hazard classes
Flammables, oxidizers, gases under pressure, pyrophoric and self-heating products, water-reactives, organic peroxides, corrosive to metals, combustible dusts, simple asphyxiants and chemicals under pressure.
- No sign-up
- Every answer explained
- Independent · not a government site
- 17 questions
- Topic drill
Study reference: CCOHS OSH Answers: WHMIS fact sheets (revised 2026-05-28), Ch. 5 WHMIS – Hazard Classes and Categories — Main concerns for each physical hazard class
All 17 questions in this test
Every question and its answer choices. The correct answers and explanations appear when you take the test above.
Why are simple asphyxiants especially dangerous in confined spaces?
- They only work in large open areas
- They are bright red and block vision
- They are colourless and odourless and give no warning
- They smell strongly and make workers panic in tight areas
A product is described as pyrophoric. What does that mean?
- It only burns when heated above 100 °C
- It must be kept in direct sunlight
- It gives off a strong smell as soon as it is opened
- It can catch fire very quickly on contact with air
Which statement about oxidizers is true?
- They burn on their own even without fuel
- They do not burn but make fires hotter and faster
- They are only dangerous when frozen
- They make fires smaller by using up the oxygen around them
Why can a cylinder of compressed gas be dangerous even if the gas is not flammable?
- Compressed gases always cause cancer
- The high pressure can make it explode if heated
- The cylinder paint is toxic
- Compressed gases react with sunlight to form acid
Which three things must come together for a fire to start?
- Fuel, oxygen and heat
- Oxygen, light and cold
- Fuel, water and pressure
- Heat, dust and metal
How can a simple asphyxiant harm a worker?
- By making metal containers corrode
- By causing cancer after many years
- By burning the skin on contact
- By pushing oxygen out of the air
Vapour from a flammable liquid drifts along the floor and is lit by a distant pilot light. The flame then travels back to the container. What is this called?
- Boil-over
- Sublimation
- Backdraft
- Flashback
A label says the product releases flammable gas in contact with water. What is the risk?
- Water makes the product completely safe
- Water causes the product to lose its smell
- Water can release a gas that may ignite
- Water turns the product into a solid
How do self-heating substances differ from pyrophoric products?
- They never catch fire under any condition
- They ignite only after a longer time or in large amounts
- They only react when mixed with water
- They ignite instantly on contact with air, even in tiny amounts
What is the special hazard of a refrigerated liquefied gas?
- It is very cold and can cause cryogenic burns
- It turns into a solid that blocks drains
- It glows and can damage eyesight
- It is very hot and can cause steam burns
What is the main hazard of products in the flammable liquids class?
- Fire or explosion
- Skin allergy
- Radiation burns
- Hearing loss
What does the "corrosive to metals" class warn about?
- The product makes metal tools magnetic
- The product rusts only plastic containers
- The product can chemically damage or destroy metal
- The product is safe for skin but not metal
What is the class "physical hazards not otherwise classified" for?
- Health effects that appear years after the first exposure
- Reaction hazards not covered by any other physical class
- Products too small to need a label
- Products whose supplier is unknown
Which product fits the WHMIS class "chemicals under pressure"?
- A gas cylinder filled with compressed oxygen for welding
- A liquid pressurized with gas in a non-aerosol container
- A liquid in an open bucket
- A spray can of air freshener
Why are combustible dusts a hazard?
- Dust always contains infectious organisms
- Dust blocks radio signals at work
- Dust reacts with water to form acid
- Fine particles in the air can ignite or explode
How does an oxidizer create a fire hazard?
- It absorbs heat and puts fires out
- It makes a fire produce less smoke
- It only burns when mixed with water
- It can cause or intensify a fire
What is the key hazard of organic peroxides?
- They cause hearing loss over time
- They may cause a fire or explosion if heated
- They freeze skin on contact
- They are harmful only to fish and other aquatic life
Physical hazard classes: key rules to remember
Our summary of what the official handbook says on this topic, in our own words. Read it before or after the practice questions above, then check the original chapter. Read the official chapter ↗
Main concerns for each physical hazard class
- Flammable gases, aerosols, flammable liquids, flammable solids: ignite easily; main hazards fire or explosion. Aerosols class also has a non-flammable category (may burst when heated).
- Oxidizing gases, liquids, solids: may cause or intensify a fire or cause fire/explosion.
- Gases under pressure: compressed, liquefied, dissolved gases hazardous because of high pressure; container may explode if heated. Refrigerated liquefied gases are very cold and can cause cryogenic (cold) burns.
- Self-reactive substances and mixtures: may react on their own to cause fire/explosion, or when heated.
- Pyrophoric liquids/solids: catch fire very quickly (spontaneously) if exposed to air.
- Self-heating substances: may catch fire if exposed to air, but only after a longer time or in large amounts (differs from pyrophorics).
- Substances which, in contact with water, emit flammable gases: react with water to release flammable gas, sometimes igniting spontaneously.
- Organic peroxides: may cause fire or explosion if heated.
- Corrosive to metals: may chemically damage or destroy metals.
- Combustible dusts: finely divided solid particles that may catch fire or explode if dispersed in air and ignited.
- Simple asphyxiants: gases that may displace oxygen and cause rapid suffocation.
- Physical hazards not otherwise classified: hazards from a chemical reaction that cause serious injury or death at the time of the reaction; hazard statement describes the hazard.
- Chemicals under pressure: liquids or solids in a receptacle (not an aerosol dispenser) pressurized with a gas at 200 kPa gauge or more at 20 °C, excluding gases under pressure.
supporting facts
- Fire needs fuel, oxygen and heat (ignition source) together.
- Vapour of most flammable liquids is heavier than air; can travel along floor to a distant ignition source and flash back.
- Static charge builds when flammable liquids are poured, pumped, filtered, stirred or flow in pipes; can ignite.
- Air is about 21% oxygen. Oxidizers do not burn themselves but make fires hotter and faster and can make materials burn that normally would not.
- Simple asphyxiants are colourless, odourless; low oxygen (19.5% or less) causes symptoms; concern in confined spaces. No pictogram (not in GHS); signal word Warning.
- Damaged gas cylinders can rocket or spin if a valve breaks.
Other topics
- What WHMIS isWhat the Workplace Hazardous Materials Information System is, its four main parts, how it lines up with the GHS, what counts as a hazardous product and which products are excluded.
- WHMIS law and enforcementWHMIS 1988, WHMIS 2015 and the December 2022 amendments, the Hazardous Products Act and Regulations, who enforces WHMIS in each jurisdiction and what an inspector checks.
- Supplier, employer and worker dutiesWho counts as a supplier, manufacturer, importer or distributor, what employers must provide, what workers must do, and the role of the health and safety committee.
- WHMIS education and trainingThe difference between education and site-specific training, who must be trained, what it must cover, the four questions every worker should be able to answer, reviews and refreshers.
- Hazard groups, classes and categoriesThe physical and health hazard groups, how classes group similar products, how categories and types show severity, and what changed in the 2022 amendments.
- Health hazard classesAcute toxicity, skin and eye damage, sensitizers, mutagens, carcinogens, reproductive toxicity, target organ toxicity, aspiration hazard and biohazardous infectious materials.
- WHMIS pictogramsThe red-bordered diamond pictograms described in words: flame, flame over circle, gas cylinder, corrosion, exploding bomb, skull and crossbones, health hazard, exclamation mark and the biohazard symbol, plus classes with no pictogram.
- Supplier labelsThe required parts of a supplier label, the two signal words, hazard and precautionary statements, bilingual rules, small-container exemptions and the 180-day update rule.
- Workplace labels and other identificationWhen a workplace label is needed (decanting, products made on site, lost labels), the decanting exceptions, what a workplace label must say, and other means of identification.
- Safety data sheets (16 sections)What an SDS is, the 16 sections in their required order, which sections workers use most, update rules, and the employer's duty to keep SDSs available.
- Safe handling and storageEveryday precautions by pictogram: ventilation, ignition sources, incompatibles, gas cylinders, corrosives, toxic products, storage height, cabinets and controls such as substitution and PPE.
- Emergencies, spills and first aidWhere emergency information is on the SDS, reporting leaks and spills, fire and evacuation basics, eyewash and showers, and standard first-aid steps by route of exposure.
- Ontario WHMIS rules (Regulation 860)How Ontario applies WHMIS through the Occupational Health and Safety Act and Regulation 860: who is covered, decanted containers, SDS access, annual review of training, exemptions and hazardous waste.